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  Lionel Chem-Lab - Chapter 26

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NOTE:  This book was published in 1942 as a manual to accompany several Lionel Chemistry sets of the time.  While some of the experiments and activities here may be safely done as written, a number of them use chemicals and methods no longer considered safe.  In addition, much of the information contained in this book about chemistry and other subjects is outdated and some of it is inaccurate.  Therefore, this book is probably best appreciated for its historical value rather than as a source for current information and good experiments.  If you try anything here, please understand that you do so at your own risk.  See our Terms of Use.
Pages 283 - 288

CHAPTER XXVI

CHEMISTRY OF SOILS AND FERTILIZERS

Soil is chiefly a product of the weathering of rock and consequently varies greatly in composition and physical properties. "Weathering of rock" refers to the natural action of the weather: rain, wind and air - which have a very powerful grinding effect on rock structure.

Limestone soil results from the disintegration of limestone. Other soils of sandy and clay type are rich in silicates. Acidity is also a characteristic of certain soils. This is due to the decaying of plant and vegetable matter in the ground and the subsequent forming of acid products. Inasmuch as crops do not thrive on such soil, it becomes necessary for the chemist to devise a satisfactory method for keeping the soil sweet. This the farmers in many sections of the country do by using calcium hydroxide or ground limestone to neutralize the acid condition.

FERTILIZERS

Plants derive their nourishment from both soil and air, but the soil is the more important of the two. It is vital, therefore, that land for agricultural purposes contain the proper constituents to encourage the growth of plant life. When a plant grows, it utilizes certain food elements in the soil and thus in order to maintain the fertility of the soil in subsequent years, it becomes necessary to return these elements to the ground. This is the purpose of fertilizers.

In our chapter on nitrogen we emphasized the importance of the nitrates to plant growth. Nitrogenous material is one of the most important materials used to maintain the fertility of the soil. Phosphates of calcium and potassium are other frequently used ingredients.

Nitrogenous matter may be obtained from a number of different sources, principally “natura1" fertilizers or the waste products of animals, refuse from slaughterhouses, and pure chemical compounds such as calcium cyanamide and sodium nitrate.

Due to the scarcity of many of the nitrates, the converting of the natural nitrogen in the air by the process known as the fixation of nitrogen promises in the future to supply more and more of our requirements for nitrogenous compounds.  

Calcium phosphate is an important ingredient used in the manufacture of fertilizers. Small quantities can be obtained by grinding bones. The prin-

283


284 SOILS AND FERTILIZERS

cipal source, however, is the rich phosphate quarries in Florida and Tennessee where phosphate rock is actually mined from the ground.

nitrate plant

An air view of a huge nitrate plant in Hopewell, Virginia. It is here that great quantities of nitrate of soda are produced to be used to restore the fertility of farm fields sterilized by repeated crop cultivation.

EXPERIMENT No. 778 A Mineral Fertilizer

(CL-77)

APPARATUS: Sodium borate, trisodium phosphate, ammonium chloride, aluminum sulfate, ferric ammonium sulfate, manganese sulfate, ammonium hydroxide, magnesium sulfate, calcium carbonate, potassium carbonate, a container, and measuring spoon.

PROCEDURE: Place in a large container one measure of sodium borate, six measures of trisodium phosphate, two measures of ammonium chloride, one measure of aluminum sulfate, one measure of ferric ammonium sulfate, one half measure of manganese sulfate, six drops of ammonium hydroxide, one measure of magnesium sulfate and one measure of calcium carbonate. Pour into this one quart of warm water and two measures of potassium carbonate. Sprinkle this over the house plants. After a reasonable time, an improvement will be noted in the general condition of these plants.

EXPERIMENT No. 779 Making A Garden Fertilizer

(CL-11, CL-22, CL-33, CL-44, CL-55, CL-66, CL-77)

LIONEL CHEM-LAB 285

APPARATUS: Wood ash, poultry manure and tin can.

PROCEDURE: Mix in a clean tin can two parts of wood ash with one part of poultry manure. Insert a tablespoonful of this into the soil around the roots of a leafy garden plant. Within a reasonable time the general condition of the plant will improve.

EXPERIMENT No. 780 How Carbon Dioxide Affects Plant Growth

(CL-11, CL-22, CL-33, CL-44, CL-55, CL-66, CL-77)

APPARATUS: Two mason jars, soil, beans, vinegar, baking soda, a milk bottle, drinking glass and teaspoon.

PROCEDURE: In each mason jar, place two inches of damp soil. Then plant three or four beans in each jar. Prepare some carbon dioxide in a quart milk bottle by mixing two teaspoonfuls of baking soda with a half glass of vinegar. Transfer the carbon dioxide to one of the jars by pouring it. Be careful not to transfer any of the liquid. Label this jar so as to distinguish it from the other jar which does not contain carbon dioxide. Seal both jars and set aside, noting from time to time
the jar in which the beans grow faster.

SUMMARY: Since green plants need carbon dioxide to manufacture food, the plant with the larger supply will grow the faster.

EXPERIMENT No. 781 Testing Soil For Alkalinity

(CL-11, CL-22, CL-33, CL-44, CL-55, CL-66, CL-77)

APPARATUS: Test tube, soil to be tested, red litmus paper and saucer.

PROCEDURE: Mix some soil in a saucer with enough water to form a thin paste. Insert a strip of red litmus paper and set aside for a half hour. Remove paper and rinse thoroughly. Note whether there is a change in color. If the soil is alkaline the red litmus paper will become blue.

EXPERIMENT No. 782 How To Test Soil For Acidity

(CL-11, CL-22, CL-33, CL-44, CL-55, CL-66, CL-77)

APPARATUS: Soil, test tube, blue litmus paper and saucer.

PROCEDURE: Mix a little soil in the saucer with enough water to form a thin paste. Insert a strip of blue litmus paper and set aside for a half hour. Remove the paper and rinse it thoroughly. Note whether there is a change in color. If the soil is acid, the blue litmus paper will become red.

INSECTICIDES

EXPERIMENT No. 783 A Solution Of Lime Sulfur
(CL-11, CL-22, CL-33, CL-44, CL-55, CL-66, CL-77)

APPARATUS: Calcium oxide, sulfur, glass, test tube and a candle or alcohol lamp.


286 SOILS AND FERTILIZERS

bread and growing grains with fertilizer

The Barrett Company

Even the Staff of Life may be improved upon by chemistry. The wheat which is used to produce such high quality bread as shown above greatly diminishes the fertility of American soil each year. Through modern chemistry, this fertility is restored continually by the application of nitrate of soda. The lower photograph shows the difference between a crop treated with nitrate and one left untreated.


LIONEL CHEM-LAB 287

PROCEDURE: Mix four measures of calcium oxide and two measures of sulfur in a test tube. Fill the tube halfway with water and boil until the solution becomes yellow. Dilute the solution with a half glass of water and use it as a spray on fruit trees. This solution is an effective insecticide.

EXPERIMENT No. 784 An Oil-Emulsion Insecticide

(CL-11, CL-22, CL-33, CL-44, CL-55, CL-66, CL-77)

APPARATUS: Calcium oxide, sulfur, test tube, thin motor oil, naphtha soap, candle or alcohol lamp and a beaker.

PROCEDURE: Mix two measures of calcium oxide and one measure of sulfur in a test tube. Fill the tube halfway with water and boil until the solution becomes yellow, Pour the solution into a beaker containing four teaspoonfuls of motor oil. Add a small piece of naphtha soap and boil until an emulsion forms. Dilute this with a half pint of water. This emulsion may be used to destroy "sucking" insects which are harmful to green plants.

EXPERIMENT No. 785 Sulfur As A Fungicide

(CL-66, CL-77)

APPARATUS: Sulfur, mortar and pestle, paint brush.

PROCEDURE: Grind a teaspoonful of sulfur in the mortar. Apply this powder to a mildewed plant with a paint brush. After a reasonable time the sulfur should destroy the mildew. However, in severe cases, application may have to be made more than once.

EXPERIMENT No. 786 Testing Bordeaux Mixture For Free Copper

(CL-55, CL-66, CL-77)

APPARATUS: Copper sulfate, calcium oxide, test tubes, candle or alcohol lamp, beaker, vinegar, sodium ferrocyanide, funnel and filter paper.

PROCEDURE: Place one measure of copper sulfate in a test tube one half full of water and heat to dissolve. Put four measures of calcium oxide in another test tube one half full of water and boil for a short time. Cool both test tubes and pour the solutions into a beaker or glass and stir. Filter a little of this solution into a clean test tube. Add four drops of vinegar. Place one half measure of sodium ferrocyanide in another test tube one quarter full of water and shake well. Add a few drops of this to the filtered mixture and note any color change.

SUMMARY: If the solution becomes reddish-brown, copper is present. The copper in Bordeaux mixture destroys fungi but does not injure plants.

EXPERIMENT No. 787 Making A Copper Fungicide

(CL-55, CL-66, CL-77)


288  SOILS AND FERTILIZERS


APPARATUS: Copper sulfate, calcium oxide, two test tubes, alcohol lamp or candle and a beaker.

PROCEDURE: Place one measure of copper sulfate in a test tube one half full of water and heat to dissolve. Place four measures of calcium oxide in another test tube one half full of water and boil for a short time. Cool both test tubes and pour the solutions into a beaker or glass and stir. Set this solution aside and note the precipitate which forms. The fungicide is used to kill fungi on grapevines.

EXPERIMENT No. 788 Nicotine Extract

(CL-77)

APPARATUS: Cigarette, filter paper, funnel, beaker, soap, alcohol lamp or candle and test tube.

PROCEDURE: Put some cigarette tobacco into a beaker half full of water. Boil the contents of the beaker for about ten minutes and then filter, collecting the clear liquid in the test tube. Place two measures of soap in a test tube half full of water and shake to dissolve. Pour the clear nicotine liquid into the soap solution and use as a spray for plants in the home. This mixture is an infallible insecticide.

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